Hover over the thumbnail with your cursor to expose the "+" icon. Click on it to upload custom thumbnail (upload an image from your computerfile system) or select a custom thumbnail (select from images that have already been uploaded to the collection in LUNA).
Section
Column
Column
Selecting upload custom thumbnail will open the Custom Thumbnail Selection tab. Once you have found the image you want to use as the custom thumbnail, click the "+" icon in the top right corner of the image.